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1、BRITISH STANDARD BS EN
13858:2006
Corrosion protection of metals —
Non-electrolytically applied zinc flake coatings on iron or steel components
ICS 25.220.40
2、
BS EN 13858:2006
National foreword
This British Standard is the UK implementation of EN 13858:2006. It supersedes BS EN 13858:2003 which is withdrawn.
The UK participation in its preparation was entrusted to Technical Committee
STI/33, Electrodep
3、osited and related coatings.
A list of organizations represented on this committee can be obtained on request to its secretary.
This publication does not purport to include all the necessary provisions of a contract. Users are responsible for its correct application.
Compliance with a British
4、 Standard cannot confer immunity from legal obligations.
This British Standard was published under the authority
Strategy Committee on 31 March 2008
? BSI 2008
ISBN 978 0 580 54308 1
Amendments/
5、corrigenda issued since publication
Date Comments
EUROPEAN STANDARD NORME EUROPéENNE
EUROP?ISCHE NORM
EN 13858
November 2006
ICS 25.220.40 Supersedes EN 13858:2003
English Version
Corrosion protection of metals - Non-electrolytically applied zinc flake coatings on
6、 iron or steel components
Protection des métaux contre la corrosion - Revêtements non électrolytiques de lamelles de zinc sur des composants en fer ou en acier
Korrosionsschutz von Metallen - Nicht elektrolytisch aufgebrachte schuppenf?rmige Zinküberzüge auf Werkstücken aus Eisen oder Stahl
7、
This European Standard was approved by CEN on 6 October 2006.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliogra
8、phical references concerning such national standards may be obtained on application to the Central Secretariat or to any CEN member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of
9、a CEN member into its own language and notified to the Central Secretariat has the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy,
10、 Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION C O M I Té EUR O P éEN DE NOR M A L I S A TI ON EU
11、R O P ? I S C H ES KOM I TEE F ü R NOR M UNG
Management Centre: rue de Stassart, 36 B-1050 Brussels
? 2006 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members.
Ref. No. EN 13858:2006: E
EN 13858:2006 (E)
12、
Contents Page
Foreword..............................................................................................................................................................3
Introduction ...........................................................................................
13、..............................................................4
1 Scope ......................................................................................................................................................5
2 Normative references ...............................................
14、.............................................................................5
3 Terms and definitions ...........................................................................................................................5
4 Information to be supplied by the purchaser to the processor ...
15、.....................................................6
5 Designations ..........................................................................................................................................6
6 Requirements .....................................................................
16、....................................................................8
7 Sampling .................................................................................................................................................9
Annex A (informative) Additional information concerning coatings .
17、........................................................10
Annex B (normative) Adhesion test methods...............................................................................................11
Annex C (normative) Sampling ...................................................................
18、...................................................12
Bibliography ......................................................................................................................................................13
13
Foreword
This document (EN 13858:2006) has been
19、 prepared by Technical Committee CEN/TC 262 “Metallic and other inorganic coatings”, the secretariat of which is held by BSI.
This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by May 2007, and confl
20、icting national standards shall be withdrawn at the latest by May 2007.
This document supersedes EN 13858:2003.
According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Cy
21、prus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.
Introduction
Th
22、e purpose of non-electrolytically applied zinc flake coatings, which may contain a small proportion of aluminium flakes, is for corrosion protection of steel components. If needed, these coatings may also incorporate an integral lubricant, for improving lubricity. Variations in colour o
23、r lubricity are obtained by applying a suitable supplementary coating to zinc flake-based coatings.
The non-electrolytically applied zinc flake coatings for iron and steel components are obtained by cold immersion or by pneumatic or electrostatic gun-spraying of the coating liquid, followed by c
24、uring. Coating processes by cold immersion ensure complete coverage of components, even with complex shapes. These coatings are not suitable for components that are used at temperatures higher than the curing temperature.
Mechanical cleaning methods of the metal surfaces are preferred for steels
25、parts having a tensile strength of
1 000 MPa and greater (Rm ≥ 1 000 MPa) to avoid the risk of hydrogen embrittlement. If acid chemical cleaning methods are used, stress relief heat treatment is required for high strength steels (Rm ≥ 1 000 MPa) if they contain tensile stresses (see Clause 6
26、.1.2).
Zinc protects steel by galvanic action, i.e. sacrificial action takes place to protect steel when it is in close contact with the steel, and after weathering, zinc oxides are formed on the coating surface. These oxides are voluminous and plug the pores in the coating to provide barrier pro
27、tection. Apart from cathodic corrosion protection, the zinc flakes also provide barrier properties due to the platelet structures.
Artificial atmosphere corrosion tests of these coatings can provide some measure of guidance for corrosion protection. However, the duration and results of accelerate
28、d corrosion tests, such as the neutral salt spray test, have no direct relation to the corrosion protection in other environments.
WARNING —This European Standard calls for the use of substances and/or procedures that may be injurious to health if adequate safety measures are not taken. This Euro
29、pean Standard does not address any health hazards, safety matters or environmental conditions associated with its use. It is the responsibility of the user of this European Standard to establish appropriate health and safety practices and take suitable actions for any national and International regu
30、lations.
1 Scope
This European Standard specifies requirements for non-electrolytically applied coatings, composed mainly of zinc flakes, for protection against corrosion of steel components, excluding threaded fasteners. These coatings may also be provided with integ
31、ral lubricant if needed.
NOTE 1 Requirements for threaded fasteners are given in EN ISO 10683.
The temperature and duration of curing the coating can influence the mechanical properties of components because of their change of metallurgical conditions. These coatings should not be applied to
32、components that can be used at temperatures higher than the curing temperature, unless specifically ordered.
NOTE 2 If aluminium flakes, when added to zinc flake dispersion, form a continuous bond, a high risk of hydrogen embrittlement for steels of tensile strength over 1 800 MPa may exist bec
33、ause of the sacrificial action of the coating during corrosion reactions in storage and/or in service.
2 Normative references
The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated referen
34、ces, the latest edition of the referenced document (including any amendments) applies.
EN 60454-2, Specifications for pressure-sensitive adhesive tapes for electrical purposes — Part 2: Methods of test (IEC 60454-2:1994)
EN ISO 2064:2000, Metallic and other inorganic coatings — Definitions and
35、 conventions concerning the measurement of thickness (ISO 2064:1996)
EN ISO 9227, Corrosion tests in artificial atmospheres — Salt spray tests (ISO 9227:2006)
EN ISO 16348:2003, Metallic and other inorganic coatings — Definitions and conventions concerning appearance (ISO 16348:2003)
ISO
36、2859 (all parts), Sampling procedures and tables for inspection by attributes
ISO 4519, Electrodeposited metallic coatings and related finishes — Sampling procedures for inspection by attributes
3 Terms and definitions
For the purposes of this European Standard, the terms and definition
37、s given in EN ISO 2064:2000 and
EN ISO 16348:2003 apply.
4 Information to be supplied by the purchaser to the processor
When ordering articles for non-electrolytically applied zinc flake coatings on iron or steel conforming to this European Standard, the purchaser shall provide the
38、following information in writing in the contract, purchase order or in the engineering drawing:
a) number and date of this European Standard, i.e. EN 13858: 2006;
b) designation (see clause 5);
c) specification and metallurgical condition of the component (heat treatment, hardness and/
39、or other characteristics), which may be influenced by the coating process, and any process temperature limitation;
d) significant surface and the requirement of coating thickness on the significant surface, including the coating of holes, recesses and presence of rack marks;
NOTE Requirement
40、s for coating thickness on the non-significant surface and the presence of uncoated areas can also be specified (see 6.2.1);
e) requirement of dimensional tolerances including any excesses of coatings in complicated shapes of components; these areas shall be agreed between supplier and purchas
41、er;
f) tensile strength of the component and requirement of stress relief heat treatment;
g) requirements of the type of coating processes (see Annex A), type of coating (with aluminium flakes or without aluminium flakes, see 6.1.3), coating thickness (see Table 1) and coating adhesion (see
42、 6.2.3);
h) requirement of supplementary coating, e.g. sealants, lubricants, colours, etc. (see 6.2.4);
i) requirement of accelerated corrosion test (see clause 6.3);
j) requirement of any additional tests or performance tests for lubricated coatings whether using integral coating lubrica
43、nts, or lubricants applied after coatings;
k) sampling and inspection requirements (see clause 7).
5 Designations
5.1 General
The designation shall consist of the following:
a) term “non-electrolytically applied”;
b) number of this European Standard, EN 13858;
c) hyphen (-
44、);
d) chemical symbol of the basis metal;
e) stroke (/);
f) symbols for the zinc flake coating and the method of application (see 5.4.1), as well as any coatings that may be applied prior to or after deposition, separated by strokes for each stage in the coating sequence in the order of
45、 application. The coating designation includes the thickness of the coating in micrometers (μm).
5.2 Basis metal
The basis metal shall be designated by its chemical symbol or its principal constituent if an alloy. For example, Fe for iron and steel.
The specific alloy may be
46、 identified by its standard designation (for example, its UNS number as given in ASTM DS-56G, or its national or regional equivalent) placed between the symbols “< >”, for example, Fe.
5.3 Pre-process stress relief heat treatment
Stress relief heat treatment prior to application of a
47、 coating may be required for some basis materials. Brackets shall be placed around the letters, SR, the temperature in Celsius, and the time in hours. The temperature shall be in parenthesis after the letters, SR; for example, [SR (210) 3].
5.4 Type and thickness of coatings
5.4.1 Type of coat
48、ing
i immersion application; p pneumatic application; fl flake;
yc coating with chromate;
nc coating without chromate;
T1 paints, varnishes or similar coatings; T2 organic or inorganic sealants;
T3 colour;
T4 oil or other lubricants.
5.4.2 Thickness of coating
Non-electrolyticall
49、y applied zinc flake coating, by immersion or pneumatic processes, shall be designated by the symbol "Zn" with the prefix "fl" and a further prefix "i" or “p” for immersion and pneumatic application processes respectively, followed by a number giving the minimum local thickness of the coating in μm.
50、 For example, iflZn4 or pflZn4 designate zinc flake coatings with 4 μm thickness by immersion or pneumatic processes respectively. The minimum thickness of the zinc flake coating shall be in accordance with Table 1.
5.4.3 Examples of coating designations
A non-electrolytically deposited zinc f
51、lake coating, applied by immersion process, of 4 μm thick on steel (Fe), with chromates:
Non-electrolytically applied zinc flake coating EN 13858 – Fe/iflZn4/yc
A non-electrolytically deposited zinc flake coating, without chromate, applied by pneumatic process, of 8 μm thick on high strength s
52、teel that is stress relieved at 210 °C for 3 h before the application of the coating with organic sealant (T2):
Non-electrolytically applied zinc flake coating EN 13858 – Fe/[SR(210)3]/pflZn8/nc/T2
6 Requirements
6.1 General
6.1.1 Basis material
This European Standard does not s
53、pecify requirements for the condition, finish and surface roughness of the basis metal prior to the application of non-electrolytically zinc flakes. Surfaces to be coated, however, shall be free from oxides, pitting, tool marks, intergranular attack, or other defects and shall be clean and dry. If
54、 necessary, cleaning can be by chemical or mechanical means.
NOTE When processing higher tensile parts (Rm ≥ 1 000 MPa) mechanical cleaning is preferred to ensure that no hydrogen can be absorbed by the parts.
6.1.2 Stress relief heat treatment before coating
Steel parts with an ultimate
55、tensile strength of 1 000 MPa and greater (Rm ≥ 1 000 MPa), that contain tensile stresses caused by machining, grinding or cold forming operations, shall be given a stress relief heat treatment prior to cleaning and deposition of the coating, in accordance with ISO 9587 or as specified
56、by the purchaser (see clause 4 f)).
6.1.3 Type of coating
The coating is produced by applying to the surface of a component a zinc flake dispersion, with or without addition of aluminium flakes, in a suitable liquid medium. It may or may not contain chromate or have supplementary coatings (see
57、 clause 4 g) and 4 h)).
If the coating contains aluminium flakes, it shall be specified (see 4g)).
6.1.4 Curing
The curing temperatures and duration period shall be as required for the composition of the coating material.
NOTE The temperature is generally above 180 oC and the curing peri
58、od is between 15 min to 60 min. The curing temperature and/or its duration is not a substitute for stress relief heat treatment.
6.2 Coating requirements
6.2.1 Appearance
The coating shall be present on all significant surfaces, shall be silver grey and smooth, uniform, adherent, and free
59、 from blisters, uncoated areas and other defects. The coating shall extend into holes and recesses to a distance as specified in the drawing, contract or purchase order (see 4 d)).
Approved samples shall be used for comparison purposes to control the appearance of the final finish in accordance w
60、ith EN ISO 16348.
6.2.2 Coating thickness
The coating thickness specified shall be the minimum local thickness. The thickness shall conform to the requirements of Table 1.
The minimum local thickness shall be measured using one of the methods given in EN ISO 1463, EN ISO 2064,
61、 EN ISO 2178 or EN ISO 3882.
6.2.3 Adhesion
Adhesion of the coating shall be tested by one of the appropriate methods described in EN ISO 2819, or given in Annex B.
NOTE Paint adhesion tests may indicate some lamination of the zinc-flake coating but this lamination may not be represen
62、tative of typical service performance.
6.2.4 Supplementary coatings
To increase corrosion protection, or to change the appearance or friction properties of the coating, the non- electrolytically applied zinc flake coatings can be covered by paints (conventional and electrophoretic)
63、, lacquers and lubricants in accordance with the requirements of drawing, contract or purchase order (see 4 h)).
NOTE Some zinc flake coatings are supplied with a supplementary coating as part of the system.
6.3 Accelerated corrosion test
When tested in accordance with the neutral salt spra
64、y test specified in EN ISO 9227, the articles shall show no evidence of corrosion of the basis metal when exposed for the duration given in Table 1.
Table 1 — Duration of salt spray testing for non-electrolytically deposited zinc flake coating
Minimum test duration
h
Minimum coating thic
65、kness a
μm
Coating with chromate
flZnyc
Coating without chromate
flZnnc
240
4
6
480
5
8
720
8
10
960
9
12
a A coating mass per unit area may be converted to a thickness by use of the following factors:
? coatings with chromate, 4,5 g/m2 = 1 μm thickness;
? coatings without chroma
66、te, 3,8 g/m2 = 1 μm thickness.
NOTE 1 The duration and results of artificial atmosphere corrosion tests, such as neutral salt spray test, may have little relationship to the service life of the coated article and therefore, the results obtained should not be regarded as a direct guide to the corrosion resistance of the tested coatings in all environments where these coatings may be used.
NOTE 2 It is difficult to validate the results of artificial atmosphere corrosion tests unless approp
【BS英國標準】BS EN 13858 Corrosion protection of metals — Nonelectrolytically applied zinc f
